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Organic Chemistry II CHEM-2425 Ch 17 Introduction to Carbonyl Compounds Part 1
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Chapter 17 Lecture Video Part 1
Section 17.1 Structure and Bonding: Intro to carbonyl compounds.
Section 17.2 General Reactions of Carbonyl Compounds: Identify which compounds undergo nucleophilic addition and which undergo nucleophilic substitution. Predict the relative reactivity of different compounds to nucleophilic attack. Draw the mechanism for nucleophilic addition and nucleophilic substitution.
Section 17.3 Oxidation/Reduction Reactions: Overview of oxidations and reductions related to carbonyl compounds.
Section 17.4 Reduction of Aldehydes and Ketones: Predict the product for the reduction of aldehydes and ketones with NaBH4 and LiAlH4. Draw the mechanism for reduction with metal hydrides. Predict the product of catalytic hydrogenation of aldehydes and ketones.
Section 17.5 Stereochemistry of Carbonyl Reduction: Apply previously learned principles of stereochemistry to the reduction of ketones.
Section 17.6 Enantioselective Reduction: Predict the stereochemical product when reducing a ketone with a CBS reagent.
Section 17.7 Other Metal Hydride Reducing Agents: Predict the products for reduction with DIBAL-H and lithium tri-ter-butoxyaluminum hydride.
These are the lectures that I use in my Organic Chemistry II course. The textbook I use is Smith, Janice "Organic Chemistry", McGraw Hill, 6th Ed., 2020, ISBN13: 9781260119107. Some images used in this video come from that textbook.
Section 17.1 Structure and Bonding: Intro to carbonyl compounds.
Section 17.2 General Reactions of Carbonyl Compounds: Identify which compounds undergo nucleophilic addition and which undergo nucleophilic substitution. Predict the relative reactivity of different compounds to nucleophilic attack. Draw the mechanism for nucleophilic addition and nucleophilic substitution.
Section 17.3 Oxidation/Reduction Reactions: Overview of oxidations and reductions related to carbonyl compounds.
Section 17.4 Reduction of Aldehydes and Ketones: Predict the product for the reduction of aldehydes and ketones with NaBH4 and LiAlH4. Draw the mechanism for reduction with metal hydrides. Predict the product of catalytic hydrogenation of aldehydes and ketones.
Section 17.5 Stereochemistry of Carbonyl Reduction: Apply previously learned principles of stereochemistry to the reduction of ketones.
Section 17.6 Enantioselective Reduction: Predict the stereochemical product when reducing a ketone with a CBS reagent.
Section 17.7 Other Metal Hydride Reducing Agents: Predict the products for reduction with DIBAL-H and lithium tri-ter-butoxyaluminum hydride.
These are the lectures that I use in my Organic Chemistry II course. The textbook I use is Smith, Janice "Organic Chemistry", McGraw Hill, 6th Ed., 2020, ISBN13: 9781260119107. Some images used in this video come from that textbook.
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