Gibbs Free Energy - Entropy, Enthalpy & Equilibrium Constant K

This video provides a basic introduction into Gibbs Free Energy, Entropy, and Enthalpy. It explains how to calculate the equilibrium constant K given the standard free energy change of a reaction and so much more.

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[evgenistarikov]

Dear Organic Chemistry Tutor,

First of all, many sincere thanks for your efforts!

A. There is ONLY ONE BASIC, fundamental Energy Conservation and Transformation Law. It is definitely unique and conceptually indivisible delivering two logically joint concepts - these are Energy Conservation - and Energy Transformation. Still, a more-then-100-years-old conceptual failure has brought us to two separate thermodynamic laws - but this has nothing in common with the actual physics. To come back, they have coined two more fake thermodynamic laws, employed the Probability Theory + Mathematical Statistics, and this has helped formulate the Quantum Mechanics, which is thus a basically metaphysical conceptual construction and thus ought to be only restrictedly fruitful.

B. By dividing the basically indivisible law, you are telling about Combinatorics, you are touching Probability Theory, you are even stepping back to Thermodynamics for a while, but...

You are NOT answering the poser: WHAT IS ENTROPY, sorry!

1. In the formula S = kB * ln(Ω) you imply, Ω means not a "Huge Number of Microstates", not "Probability", which numerically ranges between [0, 1], not even "Wavefunction", which ought to be a purely metaphysical notion, as it is... In effect, Ω ought to be a simplistic algebraic function of Lord Kelvin's Absolute Temperature. This result has been published 100 years ago in JACS.

2. WHAT-ENTROPY-IS-poser has been answered not by Clausius, not by Boltzmann, etc., but by Goethe, who has introduced Mephistopheles, the philosophical embodiment of ENTROPY.

3. Newton did basically know WHAT ENTROPY IS - A Counteraction.

4. That Counteractions do not grow to infinity with the growing Actions, but MUST reach their MAXIMUM values, is the result by Nicky Carnot formalized by Clausius...

5. In effect, Gibbs Energy formula renders implicit the interplay among ALL the relevant Actions (the Enthalpic term) and ALL the Counteractions (the Entropic term).

6. The standard approach you are reporting about is OK for the implicit Enthalpy-Entropy picture, employing it for studying reaction mechanism details is likewise eating soup with fork.🧐

[elpuma]

Haven't paid attention in the last 2 lectures, 45min got me right.