Nucleotide Metabolism | Pyrimidine Biosynthesis (UTP & CTP)

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Hi! Not sure if you'll notice this but I have a question. Some sources say that the pyrimidine synthesis pathway begins with carbon dioxide rather than bicarbonate. I wanted to ask, what difference does it make to have an extra hydroxyl group at the start? I'm a med student, rather than a chemistry specialist, but it interests me to know. Thank you!

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