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Total Synthesis of Cinnamodial-Based Dimer (–)-Capsicodendrin
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An organic chemistry lecture on the Total Synthesis of Cinnamodial-Based Dimer (–)-Capsicodendrin by Youngho Jang and Sunkyu Han*
Erratum:
The stereoselectivity of the epoxidation is driven by steric hindrance from the axial methyl group, not the TBS group which I say at 7:50
References:
J. Org. Chem. 2020, 85, 11, 7576–7582 (This work)
Chem. Lett. 1980,9, 445-446 (Oishi Synthesis)
J. Am. Chem. Soc. 1981, 103, 11, 3226–3228 (White Synthesis)
Socials:
Twitter: @SimplifyingSyn1
Erratum:
The stereoselectivity of the epoxidation is driven by steric hindrance from the axial methyl group, not the TBS group which I say at 7:50
References:
J. Org. Chem. 2020, 85, 11, 7576–7582 (This work)
Chem. Lett. 1980,9, 445-446 (Oishi Synthesis)
J. Am. Chem. Soc. 1981, 103, 11, 3226–3228 (White Synthesis)
Socials:
Twitter: @SimplifyingSyn1
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