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Hybridization of H2O (description of hybrid orbitals for O)
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To find the hybridization for H2O (Water) we’ll first determine the steric number. The steric number can be found by adding the number of bonded atoms and then number of lone pairs.
Steric Number = (#bonding atoms) + (#lone pairs).
You may also see it written as:
Steric Number = ( sigma bonds) + (#lone pairs).
Both equations result in a steric number of four for HOS. Therefore the hybridization for the O in H2O is sp3.
We can also use the steric number to find the molecular geometry of H2). Since we have a steric number of four bond angles will be about 109.5 degrees (less since there are lone pairs involved).
The ground state energy level diagram for H2O doesn’t explain the molecular geometry observed for H2O. However, if we consider the s and three p orbitals to be hybridized (a mix to produce four separate and equal orbitals), we can explain the observed bent molecular geometry (due to two lone pairs and two atoms bonded to the O atom). The electron geometry is tetrahedral.
There creation of hybrid orbitals is useful for understanding the shape and bond angels for molecules. To understand the energies, molecular orbital theory may be more appropriate.
Modified sp3 Hybridized Atom Image (in blue):
Steric Number = (#bonding atoms) + (#lone pairs).
You may also see it written as:
Steric Number = ( sigma bonds) + (#lone pairs).
Both equations result in a steric number of four for HOS. Therefore the hybridization for the O in H2O is sp3.
We can also use the steric number to find the molecular geometry of H2). Since we have a steric number of four bond angles will be about 109.5 degrees (less since there are lone pairs involved).
The ground state energy level diagram for H2O doesn’t explain the molecular geometry observed for H2O. However, if we consider the s and three p orbitals to be hybridized (a mix to produce four separate and equal orbitals), we can explain the observed bent molecular geometry (due to two lone pairs and two atoms bonded to the O atom). The electron geometry is tetrahedral.
There creation of hybrid orbitals is useful for understanding the shape and bond angels for molecules. To understand the energies, molecular orbital theory may be more appropriate.
Modified sp3 Hybridized Atom Image (in blue):
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