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Making High Quality Prussian Blue With HCN Gas #chemistry #cyanide #donttryathome #pigments
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I react chunks of iron covered with sodium potassium cyanide (a byproduct of the sodium potassium cyanide synthesis) with ~6M HCl to produce very fine particles of Prussian Blue. The acid reacts with the cyanide ion to produce HCN in solution. The acid also dissolves the iron producing ferrous chloride. Oxygen in solution reacts with some of that producing ferric chloride. Once Fe(II), Fe(III), and CN- are all present Prussian Blue forms and precipitates out in fine particles. This is allowed to settle, the liquid is decanted, and the solid is rinsed with water. This process is repeated several times until all of the ferric chloride solution has been removed.
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