Vibrational Rotational Spectra of Polyatomic Molecules, Effect of Nuclear Spin Statistics

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Molecular Spectroscopy Lecture series CSIR NET JRF GATE TIFR IIT-JAM
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Sir, at 15.20 mentioned about strong Q band for CH3I correspond to parallel vibration. at 31.40 sir mentioned Q line only for perpendicular vibration & answer selected as bending mode of acetylene..I heard all these thing first time. I can't understand sir..Kindly clarify it sir

Also at 34.28, sir checked with difference in band values. From that what we can conclude?

sumik.s