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Synthesis Workshop: High-valent Bismuth Redox Catalysis with Dr. Oriol Planas (Episode 36)
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In this Research Spotlight episode, we are joined by Dr. Oriol Planas, who takes us through his work in the area of bismuth catalysis!
Parent references:
Science 2020, 367, 313-317.
J. Am. Chem. Soc. 2020, 142, 11382-11387.
For footnotes, see references.
Other references (in order of appearance):
For a highlight on the benign properties of bismuth, see Nat. Chem. 2010, 2, 336.
For Bismuth in organic chemistry, see: Bismuth-Mediated Organic Reactions. (Springer, Heidelberg, 2012).
For main group redox processes, see: ChemCatChem, 2018, 10, 4213; Science 2019, 363, 479.
For pioneering work of Suzuki and co-workers on sulfone-based bismacycles, see: J. Chem. Soc., Perkin Trans. 1, 1992, 1593.
For a catalytic fluorination of organoboron compounds through SET process, see: J. Am. Chem. Soc. 2013, 135, 14012-14015.
For mechanistic considerations of negative entropies, see: Chem. Sci. 2012, 3, 72.; Inorg. Chem. 1998, 37, 3975.
For transmetallation studies to Bi(III) centers, see: Organometallics 2007, 26, 6864; Nat. Chem. 2020, 12, 260.
For pioneer studies on Bi-mediated C-O bond formation, see: Chem. Lett. 2007, 36, 928.
For studies on effects of molecular sieves in catalysis, see: J. Org. Chem. 2006, 71, 1861; Chem. Rev. 2019, 119, 12491.
Parent references:
Science 2020, 367, 313-317.
J. Am. Chem. Soc. 2020, 142, 11382-11387.
For footnotes, see references.
Other references (in order of appearance):
For a highlight on the benign properties of bismuth, see Nat. Chem. 2010, 2, 336.
For Bismuth in organic chemistry, see: Bismuth-Mediated Organic Reactions. (Springer, Heidelberg, 2012).
For main group redox processes, see: ChemCatChem, 2018, 10, 4213; Science 2019, 363, 479.
For pioneering work of Suzuki and co-workers on sulfone-based bismacycles, see: J. Chem. Soc., Perkin Trans. 1, 1992, 1593.
For a catalytic fluorination of organoboron compounds through SET process, see: J. Am. Chem. Soc. 2013, 135, 14012-14015.
For mechanistic considerations of negative entropies, see: Chem. Sci. 2012, 3, 72.; Inorg. Chem. 1998, 37, 3975.
For transmetallation studies to Bi(III) centers, see: Organometallics 2007, 26, 6864; Nat. Chem. 2020, 12, 260.
For pioneer studies on Bi-mediated C-O bond formation, see: Chem. Lett. 2007, 36, 928.
For studies on effects of molecular sieves in catalysis, see: J. Org. Chem. 2006, 71, 1861; Chem. Rev. 2019, 119, 12491.
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