mass spectrometry: tropylium ion

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For molecules that contain a benzyl group, the base peak in the mass spectrum often is the benzyl group as a fragment ion. If the benzyl group is unsubstituted, the m/z value of the fragment will be 91. Additional substituents can change this value. The prevalence of this fragment is related to the rearrangement of the benzyl cation to a stable, aromatic tropylium ion.
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