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polyprotic acids calculating pH
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A large number of acids can give two or more protons on dissociation and these are referred to as polyprotic acids.
A polyprotic acid always dissociates in a stepwise manner, one proton at a time. Note that the acid dissociation constants are labelled ka1 and ka2. The numbers on the constants refer to the particular proton of the acid that is ionizing. Thus, ka1 always refers to the equilibrium involving removal of the first proton of a polyprotic acid.
Most acids have a ka2 that is much smaller than ka1. This can be explained by the fact that the second H+ has to leave from a negatively charged species. For example in HSO3- - electrostatic attraction has to be overcomed – while the first H+ from a neutral compound H2SO3.
For more info please see:
A large number of acids can give two or more protons on dissociation and these are referred to as polyprotic acids.
A polyprotic acid always dissociates in a stepwise manner, one proton at a time. Note that the acid dissociation constants are labelled ka1 and ka2. The numbers on the constants refer to the particular proton of the acid that is ionizing. Thus, ka1 always refers to the equilibrium involving removal of the first proton of a polyprotic acid.
Most acids have a ka2 that is much smaller than ka1. This can be explained by the fact that the second H+ has to leave from a negatively charged species. For example in HSO3- - electrostatic attraction has to be overcomed – while the first H+ from a neutral compound H2SO3.
For more info please see:
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