Thermodynamics - Test 3 review - entropy change

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If I had a small quantity of compressed water in an incredibly large rigid container, will the vapor pressure of water always fill the entire volume of the container? I kinda see how this is true but I’m looking for a way or explanation to grasp this better.

jktification
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did you find the s2 and the u2 values from the saturated mixture table at 25 degrees celsius?

aubreywallace