Introduction to Asymmetric Organocatalysis: Covalent Organocatalysis

In this talk, our Resident Lecturer Dr. Aitor Maestro gives an overview of different modes of covalent organocatalysis. This episode was hosted and edited by Kathleen Cheasty.

References (in order of appearance):
Chem. Rev. 2023, 123, 4764-4794. Sci China Chem. 2023, 66, 1553-1633. Nat. Rev. Methods Primers 2021, 1, 46.
Chem. Int. 2019, 41, 12-17. Nat. Commun. 2020, 11, 3786. Eur. J. Org. Chem. 2023, 26, e2022009.
J. Am. Chem. Soc. 2000, 122, 2395-2396.
Synthesis 2017, 49, 960-972. Tetrahedron 2021, 88,132143.
J. Am. Chem. Soc. 2000, 122, 4243-4244.
Chem. Soc. Rev. 2018, 47, 278-290. Adv. Synth. Catal. 2021, 363, 629-656.
Angew. Chem. Int. Ed. 2005, 44, 4212-4215.
Angew. Chem. Int. Ed. 2005, 44, 794-797. Chem. Rev. 2019, 119, 4221-4260.
J. Am. Chem. Soc. 2005, 127, 18296-18304.
Chem. Rev. 2019, 119, 4221-4260.
Helv. Chim. Act. 1996, 79, 1899-1902.
Acc. Chem. Res. 2004, 37, 534-541. Chem. Sci. 2021, 12, 7973-7992.
J. Chem. Soc. Perkin Trans. 1 1998, 1891-1894.
J. Am. Chem. Soc. 2006, 128, 8418-8420.
Chem. Soc. Rev. 2013, 42, 4906-4917. Green Synthesis and Catalysis 2021, 2, 198-215.
Org. Lett. 2008, 10, 277-280.
J. Am. Chem. Soc. 2008, 130, 418-419.
Chem. Soc. Rev. 2011, 40, 5336-5346. Green Synthesis and Catalysis 2021, 2, 198-215.
J. Am. Chem. Soc. 1997, 119, 3836-3837.
Chem. Soc. Rev. 2014, 43, 2927-2940. Chem. Rev. 2018, 118, 9344-9411.
J. Org. Chem. 1998, 63, 5631-5635.
Chem. Rev. 2018, 118, 10049-10293. Chem. Rev. 2018, 118, 9344-9411.
Chem. Commun. 2003, 1310-1311.
Chem. Rev. 2013, 8, 6659-6690. Tetrahedron. 2017, 73, 2831-2861.
Angew. Chem. Int. Ed. 2012, 7825-7829.

References from the end:
General: asymmetric catalysis
C. R. Chimie. 2007, 10, 220-231.
Metal catalysis
Chem. Rev. 2023, 123, 4764-4794.
Sci China Chem. 2023, 66, 1553-1633.
Biocatalysis
Nat. Rev. Methods Primers 2021, 1, 46.
Organocatalysis
Chem. Int. 2019, 41, 12-17.
Nat. Commun. 2020, 11, 3786.
Curr. Sci. 2022, 122, 503.
Eur. J. Org. Chem. 2023, 26, e2022009.
Enamine & Iminium ion catalysis
J. Am. Chem. Soc. 2000, 122, 2395-2396.
J. Am. Chem. Soc. 2000, 122, 4243-4244.
Angew. Chem. Int. Ed. 2005, 44, 4212-4215.
Angew. Chem. Int. Ed. 2005, 44, 794-797.
J. Am. Chem. Soc. 2005, 127, 18296-18304.
Reviews enamine & iminium ion
Synthesis 2017, 49, 960-972.
Chem. Soc. Rev. 2018, 47, 278-290.
Chem. Rev. 2019, 119, 4221-4260.
Adv. Synth. Catal. 2021, 363, 629-656.
Tetrahedron 2021, 88,132143.
NHC catalysis
Helv. Chim. Act. 1996, 79, 1899-1902.
J. Chem. Soc. Perkin Trans. 1 1998, 1891-1894.
J. Am. Chem. Soc. 2006, 128, 8418-8420.
Org. Lett. 2008, 10, 277-280.
J. Am. Chem. Soc. 2008, 130, 418-419.
Reviews NHC
Acc. Chem. Res. 2004, 37, 534-541.
Chem. Soc. Rev. 2011, 40, 5336-5346.
Chem. Soc. Rev. 2013, 42, 4906-4917.
Chem. Sci. 2021, 12, 7973-7992.
Green Synthesis and Catalysis 2021, 2, 198-215.
Phosphine catalysis
J. Am. Chem. Soc. 1997, 119, 3836-3837.
J. Org. Chem. 1998, 63, 5631-5635.
Chem. Commun. 2003, 1310-1311.
Angew. Chem. Int. Ed. 2012, 7825-7829.
Reviews Phosphines
Chem. Rev. 2013, 8, 6659-6690.
Chem. Soc. Rev. 2014, 43, 2927-2940.
Tetrahedron. 2017, 73, 2831-2861.
Chem. Rev. 2018, 118, 10049-10293.
Chem. Rev. 2018, 118, 9344-9411.