R2.2.9 Reaction mechanisms (HL)

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This video covers how to deduce to the overall equation from the reaction mechanism and also how to deduce the rate expression from the elementary steps.
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for the question before the last one, why can step 1's reverse rate have NO3 it in but step 2's rate cannot?

reesesjoyjia
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Im confused, what is it that we would actually have to do in a question since the ib state that we dont have to propose a reaction mechanism in the current syllabus, could you please help? :)

anonmela
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Does k1 and k-1 cancel out because they are the same in equilibrium?

sachinprabhuram
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Why is the rate expression [NO2]2 if you ignore the intermediates? wouldn't it be first order?

LloydJackson-bxzc
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can I just look at the slow step and its coefficients to find the rate?

uncleparry
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So does that mean we can tell the order with respect to something based on if the slow step is uni or bimolecular?

anonmela
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You had me until the equilibrium and elimination of intermediate

Godfavorsmi